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Scientists have figured out how to turn a diamond insulator into a conductor and a semiconductor
Like the mythical Philosopher’s Stone for alchemists, diamond could be the material that will change the understanding of the production of electronics. As an international group of scientists found out, mechanical deformation turns diamonds from an insulator into semiconductors and conductors. Moreover, this transformation is reversible and controllable, which can open the way to improve almost the entire spectrum of electronic devices from transistors to solar panels.
Let us explain right away that the research data are at a very early stage, in fact, at the stage of theoretical justification and computer modeling. It is very, very far from the manufacture of any electronic devices from diamonds deformable in a controlled manner. Nevertheless, the industry for the production of artificial diamonds is developing so rapidly that the subsequent practical implementation of developments can go like clockwork.
As for the idea that underlies the project on controlled deformation of the crystal lattice, it is not new and is already used, for example, in the production of semiconductors in the form of so-called strained silicon. But in the case of the production of strained silicon, the crystal lattice is deformed by about 1% of its structure, while diamond allows deformation of up to 10% of the structure without destruction, and this allows you to sculpt from it even a semiconductor, even a conductor with the highest conductivity.
The essence of the transformation is that mechanical deformation changes the band gap of the diamond. Initially, it is very large – 5.6 electron volts. It is extremely difficult for electrons in the nodes of the crystal lattice to overcome such an energy barrier, and therefore diamond is an excellent insulator for electric current. Mechanical deformation, as shown by computer simulations using data from quantum mechanics and machine learning, changes the crystal structure of a diamond so that the band gap decreases from 5.6 electron volts to 0 and can be restored back.
In the red region of the deformed nano-needle of the diamond, the material becomes a conductor (illustration from the article)
Simply put, a diamond can become an element of a transistor gate, an LED or a very effective element of a solar panel, which, in its simplicity and efficiency, will be able to surpass all modern complex analogs.
We add that the study was carried out by scientists from the Massachusetts Institute of Technology, Nanyang Technological University (NTU) of Singapore and two Skoltech employees: Evgeny Tsymbalov and Alexander Shapeev. An article with the results of the study was published in the journal Proceedings of the National Academy of Sciences.